Mechanochemistry of fluoride solids: from mechanical activation to mechanically stimulated synthesis

Abstract This lecture text is focused on the comparatively young field of mechanochemistry fluoride solids, considering both their mechanical activation and mechanochemical synthesis. Beside a literature survey, synthesis binary fluorides MF 2 , 3 complex MMgF 4 solid solutions M x b 1− F or Ln 2+ (Ln: Y, Eu) fluorine-containing coordination polymers presented. Owing to interesting potential applications in ion conductivity luminescence properties when doped, most given examples are alkaline earth metal compounds. A short historical remarks peculiarities consequences as well necessary technical equipment for reactions precede section. Graphic abstract